Let us all take a little trip back to high school, where most of us hated Chemistry. Figuring out chemical equations like CO2 + H2O → C6H12O6 + Oor Al + HCl → AlCl3 + Hhurt my brain.

Who knew that well into my 40s, chemistry would rear its ugly head again? If you did not realize that chemistry plays a significant role in producing and aging bourbon, I am about to drop some knowledge on you.

Bourbon is made through a carefully controlled chemical process that involves several key steps, from fermentation to aging.

Here’s how chemistry is involved in each stage:

  1. Fermentation: The first step in bourbon production is the fermentation of the grain mash. The mash typically contains at least 51% corn and other grains like barley, rye, or wheat. During fermentation, yeast is added to convert the sugars in the grain into alcohol. This process, known as alcoholic fermentation, is a chemical reaction where yeast enzymes break down sugars (glucose and fructose) into ethanol (alcohol) and carbon dioxide. The specific yeast strains used in bourbon production can impact the flavor profile.
  2. Distillation: After fermentation, the mash is distilled in copper stills. Distillation is a separation process based on differences in the boiling points of alcohol and water. The alcohol is vaporized and then condensed back into liquid form, resulting in a higher alcohol content. This process concentrates the flavors and compounds from the grains and removes impurities. The choice of distillation apparatus and technique affects the chemical composition and flavor of the final product.
  3. Aging: Bourbon must be aged in new charred oak barrels, and the aging process is where chemistry plays a crucial role in developing its unique flavor. As the bourbon sits in the barrel, it undergoes several chemical reactions, including:
    • Extraction: The liquid interacts with the wood of the barrel, extracting various compounds. Vanillin (C8H8O3), tannins (C76H52O46), lignin (C81H92O28), and hemicellulose, a polymer of xylose units (C5H10O5), are some of the compounds that contribute to flavor and color.
    • Oxidation: Oxygen (O²) slowly enters the barrel through the wood, leading to oxidation reactions. These reactions can mellow harsh flavors and develop new complex flavors in the bourbon.
    • Esterification: Esters (RCOOR) are compounds formed by the reaction between alcohol and acids. During aging, esters contribute to fruity and floral notes in the bourbon.
    • Caramelization: High temperatures inside the barrel can cause caramelization of sugars in the bourbon, adding sweetness and color.
    • Evaporation and concentration: Over time, some bourbon is lost to evaporation (the “angel’s share”), concentrating the remaining liquid and intensifying its flavors.
  4. Bottling: Bourbon may be filtered and diluted with water before being bottled to achieve the desired alcohol content. Filtration can remove unwanted compounds, while dilution can affect the final flavor profile.
  5. Chemical Analysis: Throughout the production process, distillers and quality control experts use various chemical analyses to monitor and ensure the consistency and quality of bourbon. Techniques like gas chromatography, mass spectrometry, and sensory analysis are employed to detect and quantify specific compounds responsible for flavor, aroma, and color.

There you have it, Bourbon Chemistry 101. Science plays a central role in creating bourbon, from the initial fermentation to the complex chemical reactions that occur during aging, all of which contribute to this American whiskey’s distinctive taste and character.

If I had only known in high school that if I paid attention in chemistry class, one day, I could have been a distiller. All chem classes should start by announcing what jobs are possible if you pay attention.

Click here for more Original Pours. 

The Bourbon Flight Staff | + posts